多孔介质中污染物运移空间变异最优估计

论述了空间变异性分析的原理和方法,着重阐述不同估值方法在多孔介质污染物运移空间变异分析中的应用.实践表明,地质统计学方法能够弥补经典概率统计方法在评价区域化变量空间变异性方面的不足,从而对多孔介质中污染物运移的空间变异性做出更切合实际的分析与评价.     

利用工农业有机废弃物生产优质无土栽培基质

简述了无土固体基质的发展史及趋势,综述了利用工农业有机废弃物生产无土栽培基质的研究、开发和应用的现状。根据无土栽培基质的一般要求对利用工农业有机废弃物生产无土栽培基质应注意的问题进行了讨论,提出采用新技术、新工艺进行标准化生产是发展这一具有广阔前景产业的关键。     

不同生物接触氧化方法对藻类的去除效果比较及其途径分析

比较了3种生物接触氧化法对富营养化水源水中藻类的去除效果，探讨其去除藻类的途径。试验结果表明：淹没式曝气生物陶粒滤池（I型）在4-6m/h过滤速度条件下，对藻类总数的去除效率稳定，平均为70%左右；采用YDT弹性立体填料的中心导流筒曝气生物接触氧化法（Ⅱ型）与直接微孔曝气生物接触氧化法（Ⅲ型），在试验初期对藻类总数的去除率较低，平均去除率分别为60.2%、51.6%。但随着生物膜厚度的增加，试验后期对藻类的去除效果逐步得到提高，平均达70%以上。生物膜对藻类的生物絮凝、吸附、生物膜的脱落沉降等是生物接触氧化法去除藻类的主要途径。     

黄孢原毛平革菌对固体介质中染料的降解反应

用黄孢原毛平革菌(Phanerochaetechrysosporium)3品系在固体介质中建立染料的降解反应体系,分光光度法测定染料的脱色降解率。黄孢原毛平革菌在琼脂、沙子及土壤等固体介质中均能有效地降解偶氮染料、蒽醌染料及聚合染料;植物材料玉米芯和木屑可作为共代谢碳源被该菌利用;BKM F 1767菌种降解能力最强,对活性艳蓝KN R的进攻性优于对PolyR 478和比布列希猩红。     

Effects of biofilm growth on flow and transport through a glass parallel plate fracture

The effects of biofilm growth on flow and solute transport through a sandblasted glass parallel plate fracture was investigated. The fracture was inoculated using soil microorganisms. Glucose, oxygen and other nutrients were supplied to support growth. The biomass initially formed discrete clusters attached to the glass surfaces, but over time formed a continuous biofilm. From dye tracer tests conducted during biofilm growth, it was observed that channels and low-permeability zones dominated transport. The hydraulic conductivity of the fracture showed a sigmoidal decrease with time. The hydraulic conductivity was reduced by a factor of 0.033, from 18 to 0.6 cm/s, corresponding to a 72% decrease in the hydraulic aperture, from 500 to 140 microm. In contrast, the mass balance aperture, determined from fluoride tracer tests, remained relatively constant, indicating that the impact of biomass growth on effective fracture porosity was much less than the effect on hydraulic conductivity. Analyses of pre-biofilm tracer tests revealed that both Taylor dispersion and macrodispersion were influencing transport. During biofilm growth, only macrodispersion was dominant. The macrodispersion coefficient alpha(macro) was found to increase logarithmically with hydraulic conductivity reduction.     

Surfactant enhanced recovery of tetrachloroethylene from a porous medium containing low permeability lenses. 1. Experimental studies

A matrix of batch, column and two-dimensional (2-D) box experiments was conducted to investigate the coupled effects of rate-limited solubilization and layering on the entrapment and subsequent recovery of a representative dense NAPL, tetrachloroethylene (PCE), during surfactant flushing. Batch experiments were performed to determine the equilibrium solubilization capacity of the surfactant, polyoxyethylene (20) sorbitan monooleate (Tween 80), and to measure fluid viscosity, density and interfacial tension. Results of one-dimensional column studies indicated that micellar solubilization of residual PCE was rate-limited at Darcy velocities ranging from 0.8 to 8.2 cm/h and during periods of flow interruption. Effluent concentration data were used to develop effective mass transfer coefficient (Ke) expressions that were dependent upon the Darcy velocity and duration of flow interruption. To simulate subsurface heterogeneity, 2-D boxes were packed with layers of F-70 Ottawa sand and Wurtsmith aquifer material within 20-30 mesh Ottawa sand. A 4% Tween 80 solution was then flushed through PCE-contaminated boxes at several flow velocities, with periods of flow interruption. Effluent concentration data and visual observations indicated that both rate-limited solubilization and pooling of PCE above the fine layers reduced PCE recovery to levels below those anticipated from batch and column measurements. These experimental results demonstrate the potential impact of both mass transfer limitations and subsurface layering on the recovery of PCE during surfactant enhanced aquifer remediation.     

A triple-continuum approach for modeling flow and transport processes in fractured rock

This paper presents a triple-continuum conceptual model for simulating flow and transport processes in fractured rock. Field data collected from the unsaturated zone of Yucca Mountain, a repository site of high-level nuclear waste, show a large number of small-scale fractures. The effect of these small fractures has not been considered in previous modeling investigations within the context of a continuum approach. A new triple-continuum model (consisting of matrix, small-fracture, and large-fracture continua) has been developed to investigate the effect of these small fractures. This paper derives the model formulation and discusses the basic triple-continuum behavior of flow and transport processes under different conditions, using both analytical solutions and numerical approaches. The simulation results from the site-scale model of the unsaturated zone of Yucca Mountain indicate that these small fractures may have an important effect on radionuclide transport within the mountain.     

Laboratory evidence of natural remobilization of multicomponent DNAPL pools due to dissolution

Mixtures of dense non-aqueous phase liquids (DNAPLs) trapped in the subsurface can act as long-term sources of contamination by dissolving into flowing groundwater. In general, the components of higher solubility are removed more quickly, thus altering the composition of the remaining DNAPL, and possibly leading to changes in its physical properties. Through the development of a simple compositional model, Roy et al. [J. Contam. Hydrol. 2002 (59) 163] showed that preferential dissolution of a mixed DNAPL could potentially result in changes in density and interfacial tension that could subsequently lead to remobilization of an initially static DNAPL pool. The laboratory experiments presented in this next paper provide a proof-of-concept for the previously presented theory, demonstrating and quantifying this process of remobilization. In addition, the experiments provide a data set for evaluation of the model presented by Roy et al. [J. Contam. Hydrol. 2002 (59) 163]. In the four experiments, a DNAPL pool comprised of tetrachloroethene and benzene was created as an open pool overlying glass beads within a water-saturated 2-D flow box. Experiments included rectangular and triangular pools. In each of the experiments, remobilization (as breakthrough) was observed more than 2 weeks after formation of the initial pool. During each experiment, the pool height declined as mass was lost by dissolution, while sampling indicated a decrease in the mole fraction of benzene, the more soluble component. Small protuberances formed along the bottom of the pool as its composition changed with time and the displacement pressure was achieved for various pore throats. Eventually one of the protuberances extended further, forming a finger (breakthrough). In general, the pool emptied as the finger proceeded further into the beads. It was also shown theoretically and experimentally that remobilization will occur sooner for pools with a triangular (pointing down), rather than rectangular, shape. The experimental results were simulated using the model developed by Roy et al. [J. Contam. Hydrol. 2002 (59) 163]. The model matched the observations well, suggesting that it accurately represents the primary mechanisms involved with natural remobilization under the conditions of the study.     

纤维球-砂直接过滤积泥形态学的研究

本文主要研究了纤维球-砂直接过滤的积泥形态,它包括宏观和微观形态以及积泥和剩余积泥的形成过程。